Terpenes : Flavors, Fragrances, Pharmaca, Pheromones

By (author) Breitmaier, Eberhard

This concise overview of the structures of terpenes and their applications covers both the structure, natural sources, biological and pharmacological effects, as well as selected total syntheses. This book includes a chapter on structure determination, as well as added information on biogenesis, polycyclic terpenes, gingkoloids and neo-hopanes. This is an ideal introductory book for anybody starting work in this field.

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[目次]

  • Preface.1 Terpenes: Importance, General Structure, and Biosynthesis.1.1 Term and Significance.1.2 General Structure: The Isoprene Rule.1.3 Biosynthesis.2 Hemi- and Monoterpenes.2.1 Hemiterpenes.2.2 Acyclic Monoterpenes.2.3 Monocyclic Monoterpenes.2.3.1 Cyclopropane and Cyclobutane Monoterpenes.2.3.2 Cyclopentane Monoterpenes.2.3.3 Cyclohexane Monoterpenes.2.3.4 Cymenes.2.4 Bicyclic Monoterpenes.2.4.1 Survey.2.4.2 Caranes and Thujanes.2.4.3 Pinanes.2.4.4 Camphanes and Fenchanes.2.5 Cannabinoids.3 Sesquiterpenes.3.1 Farnesanes.3.2 Monocyclic Farnesane Sesquiterpenes.3.2.1 Cyclofarnesanes and Bisabolanes.3.2.2 Germacranes and Elemanes.3.2.3 Humulanes.3.3 Polycyclic Farnesane Sesquiterpenes.3.3.1 Caryophyllanes.3.3.2 Eudesmanes and Furanoeudesmanes.3.3.3 Eremophilanes, Furanoeremonphilanes, Valeranes.3.3.4 Cadinanes.3.3.5 Drimanes.3.3.6 Guaianes and Cycloguaianes.3.3.7 Himachalanes, Longipinanes, Longifolanes.3.3.8 Picrotoxanes.3.3.9 Isodaucanes and Daucanes.3.3.10 Protoilludanes, Illudanes, Illudalanes.3.3.11 Marasmanes, Isolactaranes, Lactaranes, Sterpuranes.3.3.12 Acoranes.3.3.13 Chamigranes.3.3.14 Cedranes and Isocedranes.3.3.15 Zizaanes and Prezizaanes.3.3.16 Campherenanes and Santalanes.3.3.17 Thujopsanes.3.3.18 Hirsutanes.3.4 Other Polycyclic Sesquiterpenes.3.4.1 Pinguisanes.3.4.2 Presilphiperfolianes, Silphiperfolianes, Silphinanes, Isocomanes.4 Diterpenes.4.1 Phytanes.4.2 Cyclophytanes.4.3 Bicyclophytanes.4.3.1 Labdanes.4.3.2 Rearranged Labdanes.4.4 Tricyclophytanes.4.4.1 Pimaranes and Isopimaranes.4.4.2 Cassanes, Cleistanthanes, Isocopalanes.4.4.3 Abietanes and Totaranes.4.5 Tetracyclophytanes.4.5.1 Survey.4.5.2 Beyeranes.4.5.3 Kauranes and Villanovanes.4.5.4 Atisanes.4.5.5 Gibberellanes.4.5.6 Grayanatoxanes.4.6 Cembranes and Cyclocembranes.4.6.1 Survey.4.6.2 Cembranes.4.6.3 Casbanes.4.6.4 Lathyranes.4.6.5 Jatrophanes.4.6.6 Tiglianes.4.6.7 Rhamnofolanes and Daphnanes.4.6.8 Eunicellanes and Asbestinanes.4.6.9 Biaranes.4.6.10 Dolabellanes.4.6.11 Dolastanes.4.6.12 Fusicoccanes.4.6.13 Verticillanes and Taxanes.4.6.14 Trinervitanes and Kempanes.4.7 Prenylsesquiterpenes.4.7.1 Xenicanes and Xeniaphyllanes.4.7.2 Prenylgermacranes and Lobanes.4.7.3 Prenyleudesmanes and Bifloranes.4.7.4 Sacculatanes (Prenyldrimanes).4.7.5 Prenylguaianes and Prenylaromadendranes.4.7.6 Sphenolobanes (Prenyldaucanes).4.8 Ginkgolides.5 Sesterterpenes.5.1 Acyclic Sesterterpenes.5.2 Monocyclic Sesterterpenes.5.3 Polycyclic Sesterterpenes.5.3.1 Bicyclic Sesterterpenes.5.3.2 Tricyclic Sesterterpenes.5.3.3 Tetra- and Pentacyclic Sesterterpenes.6 Triterpenes.6.1 Linear Triterpenes.6.2 Tetracyclic Triterpenes, Gonane Type.6.2.1 Survey.6.2.2 Protostanes and Fusidanes.6.2.3 Dammaranes.6.2.4 Apotirucallanes.6.2.5 Tirucallanes and Euphanes.6.2.6 Lanostanes.6.2.7 Cycloartanes.6.2.8 Cucurbitanes.6.3 Pentacyclic Triterpenes, Baccharane Type.6.3.1 Survey.6.3.2 Baccharanes and Lupanes.6.3.3 Oleananes.6.3.4 Taraxeranes, Multifloranes, Baueranes.6.3.5 Glutinanes, Friedelanes, Pachysananes.6.3.6 Taraxastanes and Ursanes.6.4 Pentacyclic Triterpenes, Hopane Type.6.4.1 Survey.6.4.2 Hopanes and Neohopanes.6.4.3 Fernanes.6.4.4 Adiananes and Filicanes.6.4.5 Gammaceranes.6.5 Other Pentacyclic Triterpenes.6.5.1 Survey.6.5.2 Stictanes and Arboranes.6.5.3 Onoceranes and Serratanes.6.6 Iridals.7 Tetraterpenes.7.1 Carotenoids.7.2 Apocarotenoids.7.3 Diapocarotenoids.7.4 Megastigmanes.8 Polyterpenes and Prenylquinones.8.1 Polyterpenes.8.2 Prenylquinones.9 Selected Syntheses of Terpenes.9.1 Monoterpenes.9.1.1 Concept of Industrial Syntheses of Monoterpenoid Fragrances.9.1.2 (R)-(+)-Citronellal.9.1.3 Rose oxide.9.1.4 Chrysanthemic Acid Methyl Ester.9.1.5 alpha-Terpineol.9.1.6 (1R,3R,4S)-(.)-Menthol.9.1.7 Camphor from alpha-Pinene.9.1.8 alpha-Pinene and Derivatives for Stereospecific Syntheses of Chiral Monoterpenes.9.1.9 Hexahydrocannabinol.9.2 Sesquiterpenes.9.2.1 beta-Selinene.9.2.2 Isocomene.9.2.3 Cedrene.9.2.4 Periplanone B.9.3 Diterpenes.9.3.1 Vitamin A (Retinol Acetate).9.3.2 Cafestol.9.3.3 Baccatin III as the Precursor of Taxol.9.4 Triterpenes.9.4.1 Lupeol.10 Isolation and Structure Elucidation.10.1 Isolation from Plants.10.2 Spectroscopic Methods of Structure Elucidation.10.3 Structure Elucidation of a Sesquiterpene.10.3.1 Double Bond Equivalents.10.3.2 Functional Groups and Partial Structures detected by 13C NMR.10.3.3 Skeletal Structure (Connectivities of Atoms).10.3.4 Relative Configuration.10.3.5 Absolute Configuration.10.4 Determination of the Crystal Structure.10.5 Molecular Structure and Odor of Terpenes.Bibliography.Survey of Important Parent Skeletons of Terpenes.Subject Index.

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この本の情報

書名 Terpenes : Flavors, Fragrances, Pharmaca, Pheromones
著作者等 Breitmaier, Eberhard
書名別名 Flavors, Fragrances, Pharmaca, Pheromones
出版元 Wiley-VCH Verlag GmbH
刊行年月 2007.01.11
ページ数 223p
大きさ H246 x W187
ISBN 9783527609949
言語 英語
出版国 ドイツ
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